Procedure / Result / Discussion
Margules, Van Laar, Wilson, NRTL
Excess Property
UNIFAC
Conclusion
Reference
VLE Data를 이용하여 열역학적 물성 분석
적합성조사
Margules, Van Laar, Wison, NRTL, UNIFAC
Plot P-x1-y1 Diagram
이성분계 분리 가능성 예측
System
Hexane/TAME ( Tertiary amyl methyl ether ; 1.1-dimethylpropyl methyl ether )
TAME
함 산소제의 한 종류
Isoolefin과 Alcohol의 반응에 의해 합성
자동차의 연료 개선을 통한 공해문제 개선
Method
Degree of Freedom
F=2-π+N=2-2+2=2
=> P, T, Comp.
Obtain the activity coeff.
using Margules, van Laar, Wilson, NRTL
Plot P-x1-y1 Diagram
using m-R’s law
- Armando del Rio, Baudilio Coto, Concepcion Pando, and Juan A. R. Renuncio,『Vapor-Liquid Equilibria for the Binary System Hexane + 1,1-Dimethylpropyl Methyl Ether at 298.15, 308.15, 318.15, and 328.15 K』, Industrial & engineering chemistry research, 2002, Vol.41 Issue 5, p1364-1369,
- Lohmann, J., Joh, R., Gmehling, J. 『From UNIFAC to Modified UNIFAC (Dortmund) 』, INDUSTRIAL AND ENGINEERING CHEMISTRY RESEARCH , 2001, Vol.40 Issue 3, p957-964,
J. M. Smith, H. C. Van Ness, M. M. Abbott.「Introduction to Chemical Engineering Thermodynamics」 7th ed. , Boston : McGraw-Hill, c2005.
- Robert H. Perry. 「Perry's chemical engineers' handbook」7th ed. , New York : McGraw-Hill, c1997.
- Palm, William J. (William John), 용호택 옮김. 「MATLAB 공학 응용」, 서울 : 아진, 1999
- O'Neil, Maryadele J. 「The Merck index : an encyclopedia of chemicals, drugs, and biologicals」13th ed., Whitehouse Station, NJ : Merck Research Laboratories, c2001.

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